• 文献标题:   Calcium hydroxyapatite in hydroxyapatite/graphene oxide/collagen nanohybrids
  • 文献类型:   Article
  • 作  者:   ZAKHAROV NA, EZHOVA ZA, KOVAL EM, TKACHEV AG, KUZNETSOV NT
  • 作者关键词:  
  • 出版物名称:   RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
  • ISSN:   0036-0236 EI 1531-8613
  • 通讯作者地址:   Russian Acad Sci
  • 被引频次:   1
  • DOI:   10.1134/S0036023615120268
  • 出版年:   2015

▎ 摘  要

Interactions between calcium and phosphorus salts, graphene oxide (GO), and collagen (COL) in aqueous solutions have been studied in the CaCl2-(NH4)(2)HPO4-NH3-H2O-GO-COL system (25A degrees C) using the solubility (residual concentrations) method and pH measurements. Syntheses were shown to yield composites comprising nanocrystalline calcium hydroxyapatite Ca-10(PO4)(6)(OH)(2)) (HA), GO, and COL of empirical formula Ca-10(PO4)(6)(OH)(2) center dot xGO center dot yH(2)O center dot zCOL (x = 0.5, 1.0, or 2.0; y = 6.5-7.7; z = 3 or 5 wt %). Some physicochemical characteristics of synthesis products and the effects of the composite formulation on the crystallographic characteristics, sizes, and morphology of nanocrystalline hydroxyapatite (NCHA) were determined and some composition-structure-dispersion-property relationships in the HA/GO/COL composites have been analyzed using chemical analysis, X-ray powder diffraction, IR spectroscopy, thermogravimetry (TGA), differential scanning calorimetry (DSC), and electron microscopy.