▎ 摘　　要

Electromagnetic interference (EMI) is an increasingly severe issue in modern life and high-performance EMI shielding materials are in desperate need. To achieve high EMI shielding effectiveness (EMI SE), a series of polybenzoxazine/graphene composites foams are developed using a simple sol-gel method. When the graphene loading increases from 1 to 20 wt%, the density of the composites foams drops from 0.4143 g/cm(3) to 0.1654 g/cm(3). Meanwhile, an electrically conductive path is formed at around 7 wt% of graphene. Below the percolation threshold, the dielectric constant increases with graphene content and composite foam with 5 wt% graphene shows dielectric constant of 10.8 (1 MHz). At the highest graphene content of 20 wt%, the electric conductivity reaches 0.02 S/cm, 10 orders of magnitude higher than pure polybenzoxazine foam. Benefiting from the high electrical conductivity and lightweight porous structure, the composite foam PF/20G delivers an EMI SE of 85 dB and a specific SE of 513.9 dB center dot cm(3)/g. Importantly, the EMI shielding is dominated by absorption attenuation, with PF/20G shows absorption ratio higher than 98% in the range of 8.4-11.0 GHz, which is believed to be caused by multiple internal reflection and absorption inside the conductive foam.