• 文献标题:   Graphene electric double layer capacitor with ultra-high-power performance
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   MILLER JR, OUTLAW RA, HOLLOWAY BC
  • 作者关键词:   electrochemical capacitor, edlc, supercapacitor, ultracapacitor, graphene
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   JME Inc
  • 被引频次:   89
  • DOI:   10.1016/j.electacta.2011.05.122
  • 出版年:   2011

▎ 摘  要

We have demonstrated, for the first time, efficient 120 Hz filtering by an electric double layer capacitor (EDLC). The key to this ultra-high-power performance is electrodes made from vertically oriented graphene nanosheets grown directly on metal current collectors. This design minimized both electronic and ionic resistance and produced capacitors having RC time-constants of less than 200 mu s. Significantly, graphene nanosheets have a preponderance of exposed edge planes that greatly increase stored charge over designs relying on basal plane surfaces. Collectively these factors make vertically oriented graphene nanosheet electrodes ideally suited for producing high-frequency EDLCs. Capacitors constructed with these electrodes are predicted to be significantly smaller than aluminum electrolyte capacitors that they could functionally replace plus be manufactured using standard semiconductor process equipment, creating interesting commercial opportunities. (C) 2011 Elsevier Ltd. All rights reserved.