• 文献标题:   Single step synthesis of graphene nanoribbons by catalyst particle size dependent cutting of multiwalled carbon nanotubes
  • 文献类型:   Article
  • 作  者:   PARASHAR UK, BHANDARI S, SRIVASTAVA RK, JARIWALA D, SRIVASTAVA A
  • 作者关键词:  
  • 出版物名称:   NANOSCALE
  • ISSN:   2040-3364 EI 2040-3372
  • 通讯作者地址:   Banaras Hindu Univ
  • 被引频次:   26
  • DOI:   10.1039/c1nr10483g
  • 出版年:   2011

▎ 摘  要

Graphene nanoribbons are emerging as an interesting material for the study of low dimensional physics and for the applications in future electronics due to its finite energy band gap. However, its applicability for large scale nanoelectronics may not be effectively realized unless graphene nanoribbons could be produced using a simple, viable, cost-effective and scalable technique. Here, we report the one step facile synthesis of few layered graphene nanoribbons (GNRs) by catalytically unzipping multi-walled carbon nanotubes (MWCNTs) based on the solubility of carbon atoms in transition metals. The process is free from aggressive oxidants (such as KMnO4, KClO4, H2SO4, HNO3, etc.) and utilizes the in situ grown nickel nanoparticles for nanotube unzipping. This is an additional advantage over previously used techniques to synthesize GNRs. To observe the effect of catalyst particle size and reaction temperature on cutting length of the nanotubes, a simulation study has been done based on solubility of carbon atoms in metal nanoparticles.