• 文献标题:   One-Pot Synthesis of Fluorescent Carbon Nanoribbons, Nanoparticles, and Graphene by the Exfoliation of Graphite in Ionic Liquids
  • 文献类型:   Article
  • 作  者:   LU J, YANG JX, WANG JZ, LIM AL, WANG S, LOH KP
  • 作者关键词:   carbon nanoribbon, carbon nanoparticle, graphene, electrochemistry, ionic liquid, fluorescent nanoparticle
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Natl Univ Singapore
  • 被引频次:   757
  • DOI:   10.1021/nn900546b
  • 出版年:   2009

▎ 摘  要

In this work we demonstrate a facile means to generate fluorescent carbon nanoribbons, nanoparticles, and graphene from graphite electrode using ionic liquid-assisted electrochemical exfoliation. A time-dependence study of products exfoliated from the graphite anode allows the reconstruction of the exfoliation mechanism based on the interplay of anodic oxidation and anion intercalation. We have developed strategies to control the distribution of the exfoliated products. In addition, the fluorescence of these carbon nanomaterials can be tuned from the visible to ultraviolet region by controlling the water content in the ionic liquid electrolyte,