• 文献标题:   Solvothermal synthesis of N-doped graphene supported PtCo nanodendrites with highly catalytic activity for 4-nitrophenol reduction
  • 文献类型:   Article
  • 作  者:   ZHANG XF, ZHU XY, FENG JJ, WANG AJ
  • 作者关键词:   solvothermal method, nitrogendoped graphene, nanodendrite, linagliptin, 4nitrophnol
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Zhejiang Normal Univ
  • 被引频次:   26
  • DOI:   10.1016/j.apsusc.2017.09.200
  • 出版年:   2018

▎ 摘  要

A simple solvothermal method was developed to prepare N-doped reduced graphene oxide supported homogeneous PtCo nanodendrites (PtCo NDs/N-rGO), where ethylene glycol (EG) served as the reducing agent and the solvent, and linagliptin as the structure-directing and stabilizing agent for PtCo NDs and dopant for rGO, respectively. Controlled researches showed that the dosage of linagliptin and the ratios of the two metal precursors were important in the current synthesis. The PtCo NDs/N-rGO nanocomposite exhibited higher catalytic activity towards the reduction of 4-nitrophnol (4-NP) in contrast with the referenced Pt-1 Co-3 NCs/N-rGO, Pt3Co1 NCs/N-rGO and commercial Pt/C catalysts. More importantly, the constructed catalyst exhibited the superior stability without sacrificing the catalytic activity, showing great prospect for the reduction of 4-NP in practice. (C) 2017 Elsevier B.V. All rights reserved.