• 文献标题:   The excellent performance of amorphous Cr2O3, SnO2, SrO and graphene oxide-ferric oxide in glucose conversion into 5-HMF
  • 文献类型:   Article
  • 作  者:   ZHANG ML, SU KM, SONG HM, LI ZH, CHENG BW
  • 作者关键词:   amorphous metal oxide, gofe2o3, 5hmf, glucose, emimbr
  • 出版物名称:   CATALYSIS COMMUNICATIONS
  • ISSN:   1566-7367 EI 1873-3905
  • 通讯作者地址:   Tianjin Polytech Univ
  • 被引频次:   27
  • DOI:   10.1016/j.catcom.2015.05.024
  • 出版年:   2015

▎ 摘  要

Amorphous Cr2O3, SnO2 and SrO presented an excellent performance in the conversion of glucose to 5-hydroxymethylfurfural (5-HMF), and 5-HMF yields achieved 84%, 81% and 99%, however, the calcined metal oxides almost completely lost the catalytic activities. Although Fe2O3 exhibited yew poor catalytic activity, the graphene oxide-Fe2O3 (GO-Fe2O3) displayed a better performance in catalytic glucose conversion to 5-HMF (86% yield) in 1-ethyl-3-methylimidazolium bromide ([EMIM]Br). The plausible mechanisms of glucose conversion to 5-HMF over amorphous Cr2O3, SnO2, SrO and GO-Fe2O3 were proposed. (C) 2015 Elsevier B.V. All rights reserved.