• 文献标题:   Tape casting of alumina/zirconia suspensions containing graphene oxide
  • 文献类型:   Article
  • 作  者:   RINCON A, CHINELATTO ASA, MORENO R
  • 作者关键词:   graphene, aluminazirconia, tape casting, suspension, rheology
  • 出版物名称:   JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
  • ISSN:   0955-2219 EI 1873-619X
  • 通讯作者地址:   CSIC
  • 被引频次:   15
  • DOI:   10.1016/j.jeurceramsoc.2013.12.027
  • 出版年:   2014

▎ 摘  要

The introduction of carbon derivatives (nanotubes, graphene, etc.) as a second phase in ceramic matrices has limitations arising from their difficult processing. This paper studies the colloidal stability and the rheological behaviour of concentrated suspensions of alumina with 5 vol.% Y-TZP (AZ) and the effect of the addition of 2 vol.% of graphene oxide (AZGO) on the suspension stability, rheological behaviour and tape casting performance. The colloidal stability was studied using zeta potential measurements in terms of concentration of deflocculants and pH and homogenisation was optimised adjusting the sonication mode and time. The best results were obtained for pulsed mode. The optimum rheological properties were obtained for solid loadings of 53 vol.% and 40 vol.% for AZ and AZGO. Homogeneous, flexible tapes with thickness of similar to 120 mu m were obtained reaching densities of >60% of theoretical density in which secondary phases are well dispersed. (C) 2013 Elsevier Ltd. All rights reserved.