• 文献标题:   Transparent and flexible electrode composed of a graphene multilayer interlayer-doped with MoO3
  • 文献类型:   Article
  • 作  者:   CHO E, CHA S, KIM Y, KIM C
  • 作者关键词:   graphene, chargetransfer doping, moo3, transparent electrode, flexible electrode
  • 出版物名称:   ORGANIC ELECTRONICS
  • ISSN:   1566-1199 EI 1878-5530
  • 通讯作者地址:   Seoul Natl Univ
  • 被引频次:   1
  • DOI:   10.1016/j.orgel.2019.105437
  • 出版年:   2020

▎ 摘  要

We demonstrate a flexible and transparent electrode consisting of a graphene multilayer that is interlayer-doped by layers of MoO3, a material that has attractive features as a graphene dopant but has not been used as such due to difficulties in fabrication. The fabrication of MoO3-interlayer-doped graphene multilayer (M-i-d GML) is enabled by successive applications of a modified wet-transfer of a graphene monolayer onto an elastomeric stamp precoated with a diffusion-blocking layer and its subsequent transfer onto a thermally evaporated MoO3 layer. By performing Raman spectroscopy and sheet resistance measurements, we show that charge-transfer doping of graphene occurs at both the top and bottom graphene-MoO3 interfaces of each graphene layer in a Mi-d GML. In comparison with a graphene multilayer doped only by a top MoO3 layer, M-i-d GMLs suffer less from the trade-off between optical transmittance and sheet resistance. Moreover, the characteristics of a green phosphorescent organic light-emitting device (OLED) employing a M-i-d GML bottom electrode are very similar to those of an OLED with an indium tin oxide anode, indicating that M-i-d GMLs are a promising candidate for transparent and flexible electrodes in optoelectronic and wearable applications.