• 文献标题:   Fe3O4 wrapped by reduced graphene oxide as a high-performance anode material for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   BENGONO DAM, ZHANG B, YAO YY, TANG LB, YU WJ, ZHENG JC, CHU DW, LI JY, TONG H
  • 作者关键词:   iron oxide, metalorganic framework, reduced graphene oxide, composite, lithiumion batterie
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:   Cent South Univ
  • 被引频次:   13
  • DOI:   10.1007/s11581-019-03346-1
  • 出版年:   2020

▎ 摘  要

Iron oxide has been considered as one of the most promising anode materials for lithium-ion batteries (LIBs) due to its low cost, environmental benignity, and abundant source. However, the huge volume variation of iron oxide during the lithiation/delithiation processes has caused a structural failure and decay of the electrochemical performance for LIBs. In order to improve the electrochemical performance of iron oxide, one efficient strategy is to prepare carbon-coated iron oxide with special structure. Herein, we use metal-organic frameworks to prepare Fe3O4/reduced graphene oxide (rGO) nanocomposite through a hydrothermal route. As an anode material of LIBs, the prepared Fe3O4/rGO nanocomposite exhibits a high discharge capacity of 1762.1 mAh g(-1) and remarkably good rate performance with a charge capacity of 1060.6 mAh g(-1) at 100 mA g(-1) and 772.9 mAh g(-1) at 1000 mA g(-1). In the Fe3O4/rGO composite, the electrical conductivity was enhanced and the volume expansion was also restrained by rGO.