• 文献标题:   Significant improved electrochemical performance of layered Li1.2Mn0.54Co0.13Ni0.13O2 via graphene surface modification
  • 文献类型:   Article
  • 作  者:   CHENG JL, LI XH, HE ZJ, WANG ZX, GUO HJ, PENG WJ
  • 作者关键词:   cathode material, graphene, surface modification, lithium ion battery
  • 出版物名称:   MATERIALS TECHNOLOGY
  • ISSN:   1066-7857 EI 1753-5557
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   4
  • DOI:   10.1080/10667857.2016.1219086
  • 出版年:   2016

▎ 摘  要

The Li1.2Mn0.54Ni0.13Co0.13O2 particles were modified by graphene to improve the electrochemical properties. The graphene-coated materials have been synthesised by spray drying method and show crystal structure similar to that of pristine. The structure, morphology and electrochemical performances of the pristine and graphene-coated materials have been investigated by Scanning electron microscopy, Transmission electron microscope, as well as charge-discharge measurements. At 250 mA g(-1), the pristine and graphene-coated samples deliver capacities of 156-178 mA h g(-1) with capacity retention of 80-90% in 100 cycles, respectively. An analysis of the charge-discharge capacity values and Ac impedance spectroscopy reveals that the improved electrochemical performances of the graphene-coated sample are due to the suppression of charge-transfer resistance and the enhancement of diffusion coefficients (D) of lithium ions.