• 文献标题:   Preparation of novel cross-linked graphene oxide membrane for desalination applications using (EDC and NHS)-activated graphene oxide and PEI
  • 文献类型:   Article
  • 作  者:   PARSAMEHR PS, ZAHED M, TOFIGHY MA, MOHAMMADI T, REZAKAZEMI M
  • 作者关键词:   carbon nanomaterial, graphene oxide go, go membrane, crosslinking, desalination
  • 出版物名称:   DESALINATION
  • ISSN:   0011-9164 EI 1873-4464
  • 通讯作者地址:   IUST
  • 被引频次:   9
  • DOI:   10.1016/j.desal.2019.114079
  • 出版年:   2019

▎ 摘  要

A novel cross-linked graphene oxide (GO) membrane was prepared by vacuum filtration using a two-step method, including activation of GO carboxyl groups by a mixture of 1-Ethyl-3- (3-dimethylaminopropyl) carbodiimide (EDC) and N -Hydroxysuccinimide (NHS) and then cross-linking with polyethyleneimine (PEI). In the cross-linking process, the activated carboxyl groups of GO react with amine groups of PEI through a simple and efficient method. GO cross-linking with PEI significantly improves membrane dimensional stability and salt rejection. The rejection of the cross-linked GO membrane was evaluated by NaCl, Na2SO4 and MgCl2 solutions, and the obtained results followed the order of R (MgCl2) > R (NaCl) > R (Na2SO4). The prepared cross-linked GO membrane was characterized by FFIR, XRD, SEM, FESEM, EDS, WCA, AFM and BET analysis. Also, the effects of operating parameters such as N-2 pressure, feed temperature and pH on the cross-linked GO membrane performance were investigated.