• 文献标题:   A Facile Approach to Chemically Modified Graphene and its Polymer Nanocomposites
  • 文献类型:   Article
  • 作  者:   ZAMAN I, KUAN HC, MENG QS, MICHELMORE A, KAWASHIMA N, PITT T, ZHANG LQ, GOUDA S, LUONG L, MA J
  • 作者关键词:   graphene, nanocomposite, electrical conductivity, toughening, epoxie
  • 出版物名称:   ADVANCED FUNCTIONAL MATERIALS
  • ISSN:   1616-301X EI 1616-3028
  • 通讯作者地址:   Univ S Australia
  • 被引频次:   157
  • DOI:   10.1002/adfm.201103041
  • 出版年:   2012

▎ 摘  要

A scalable approach for the mass production of chemically modified graphene has yet to be developed, which holds the key to the large-scale production of stable graphene colloids for optical electronics, energy conversion, and storage materials, catalysis, sensors, composites, etc. Here, a facile approach to fabricating covalently modified graphene and its polymer nanocomposites is presented. The method involves: i) employing a common furnace, rather than a furnace installed with a quartz tube and operated in inert gas as required in previous studies, to treat a commercial graphite intercalation compound with thermal shocking and ultrasonication and fabricate graphene platelets (GnPs) with a thickness of 2.51 +/- 0.39 nm that contain only 7 at% oxygen; ii) grafting these GnPs with a commercial, long-chain surfactant, which is able to create molecular entanglement with polymer matrixes by taking advantage of the reactions between the epoxide groups of the platelets and the end amine groups of the surfactant, to produce chemically modified graphene platelets (m- GnPs); and iii) solution-mixing m-GnPs with a commonly used polymer to fabricate nanocomposites. These m-GnPs are well dispersed in a polymer with highly improved mechanical properties and a low percolation threshold of electrical conductivity at 0.25 vol%. This novel approach could lead to the future scalable production of graphene and its nanocomposites.