• 文献标题:   Efficient 3D Conducting Networks Built by Graphene Sheets and Carbon Nanoparticles for High-Performance Silicon Anode
  • 文献类型:   Article
  • 作  者:   ZHOU XS, YIN YX, CAO AM, WAN LJ, GUO YG
  • 作者关键词:   lithiumion batterie, 3d conducting network, silicon, graphene, carbon nanoparticle, anode material
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   115
  • DOI:   10.1021/am3005576
  • 出版年:   2012

▎ 摘  要

The utilization of silicon particles as anode materials for lithium-ion batteries is hindered by their low intrinsic electric conductivity and large volume changes during cycling. Here we report a novel Si nanoparticle-carbon nanoparticle/graphene composite, in which the addition of carbon nanoparticles can effectively alleviate the aggregation of Si nanoparticles by separating them from each other, and help graphene sheets build efficient 3D conducting networks for Si nanoparticles. Such Si-C/G composite shows much improved electrochemical properties in terms of specific capacity and cycling performance (ca. 1521 mA h g(-1) at 0.2 C after 200 cycles), as well as a favorable high-rate capability.