• 文献标题:   Local charge transport properties of hydrazine reduced monolayer graphene oxide sheets prepared under pressure condition
  • 文献类型:   Article
  • 作  者:   RYUZAKI S, MEYER JAS, PETERSEN S, NORGAARD K, HASSENKAM T, LAURSEN BW
  • 作者关键词:  
  • 出版物名称:   APPLIED PHYSICS LETTERS
  • ISSN:   0003-6951 EI 1077-3118
  • 通讯作者地址:   Kyushu Univ
  • 被引频次:   3
  • DOI:   10.1063/1.4895072
  • 出版年:   2014

▎ 摘  要

Charge transport properties of chemically reduced graphene oxide (RGO) sheets prepared by treatment with hydrazine were examined using conductive atomic force microscopy. The current-voltage (I-V) characteristics of monolayer RGO sheets prepared under atmospheric pressure followed an exponentially increase due to 2D variable-range hopping conduction through small graphene domains in an RGO sheet containing defect regions of residual sp(3) carbon clusters bonded to oxygen groups, whereas RGO sheets prepared in a closed container under moderate pressure showed linear I-V characteristics with a conductivity of 267.2-537.5 S/m. It was found that the chemical reduction under pressure results in larger graphene domains (sp(2) networks) in the RGO sheets when compared to that prepared under atmospheric pressure, indicating that the present reduction of GO sheets under the pressure is one of the effective methods to make well-reduced GO sheets. (C) 2014 AIP Publishing LLC.