• 文献标题:   Electrochemical performance of 2D polyaniline anchored CuS/Graphene nano-active composite as anode material for lithium-ion battery
  • 文献类型:   Article
  • 作  者:   IQBAL S, BAHADUR A, SAEED A, ZHOU KB, SHOAIB M, WAQAS M
  • 作者关键词:   graphene/polyaniline/cus, nanocomposite, lithiumion battery, anode material, electrochemical performance
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797 EI 1095-7103
  • 通讯作者地址:   Quaid I Azam Univ
  • 被引频次:   17
  • DOI:   10.1016/j.jcis.2017.04.082
  • 出版年:   2017

▎ 摘  要

Lithium-ion battery (LIB) is a revolutionary step in the electric energy storage technology for making green environment. In the present communication, a LIB anode material was constructed by using graphene/polyaniline/CuS nanocomposite (GR/PANI/CuS NC) as a high-performance electrode. Initially, pure covellite CuS nanoplates (NPs) of the hexagonal structure were synthesized by hydrothermal route and then GR/PANI/CuS NC was fabricated by in-situ polymerization of aniline in the presence of CuS NPs and graphene nanosheets (GR NSs) as host matrix. GR/PANI/CuS NC-based LIB has shown the superior reversible current capacity of 1255 mAh g(-1), a high cycling stability with more than 99% coulombic efficiency over 250 cycles even at a high current density of 5 Ag-1, low volume expansion, and excellent power capabilities. Galvanostatic charge/discharge tests and cyclic voltammetry analysis were used to investigate electrochemical properties. The electrochemical test proves that GR/PANI/CuS NC is promising anode material for LIB. The crystal phases and purity of the GR/PANI/CuS NC were confirmed by X-ray diffraction (XRD). Scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray (EDX) and X-ray photoelectron spectroscopy (XPS) were employed to examine the morphology, size, chemical composition, and phase structure of the synthesized GR/PANI/CuS NC. (C) 2017 Published by Elsevier Inc.