• 文献标题:   Simple Portable Voltammetric Sensor Using Anodized Screen-Printed Graphene Electrode for the Quantitative Analysis of p-Hydroxybenzoic Acid in Cosmetics
  • 文献类型:   Article
  • 作  者:   CHAROENKITAMORN K, SIANGPROH W, CHAILAPAKUL O, OYAMA M, CHANEAM S
  • 作者关键词:  
  • 出版物名称:   ACS OMEGA
  • ISSN:   2470-1343
  • 通讯作者地址:  
  • 被引频次:   4
  • DOI:   10.1021/acsomega.2c01434
  • 出版年:   2022

▎ 摘  要

Screen-printed graphene electrodes (SPGEs) have become a potential option in electrochemical applications because of their outstanding properties and disposable approach to miniaturize the electrodes for onsite analysis. Herein, the detection of para-hydroxybenzoic acid (PHBA) in cosmetics using the anodized SPGE has been pioneered and reported. The simple anodization of the SPGE surface was operated by anodic pretreatment at a constant potential on SPGE. The surface morphologies and electrochemical behaviors of anodized SPGEs in different anodization electrolytes were examined. Using anodized SPGE in a phosphate-buffered solution, a nontoxic solution, the sensitivity of PHBA detection was significantly improved compared with pristine SPGE owing to the increase of the polar oxygen-containing functional group during the anodization. The anodized SPGE could detect a PHBA down to 0.073 mu mol/L. Finally, the developed anodized SPGE presented high ability and feasibility for PHBA detection in cosmetics. Furthermore, a facile electrode preparation step with a nontoxic solution can present high reproducibility and compatibility with a portable potentiostat for onsite PHBA detection during manufacturing.