• 文献标题:   Graphene oxide as a radiation sensitive material for XPS dosimetry
  • 文献类型:   Article
  • 作  者:   TORRISI L, SILIPIGNI L, CUTRONEO M, TORRISI A
  • 作者关键词:   graphene oxide, reduced graphene oxide, xps analysi, dosimeter, soft xray dose
  • 出版物名称:   VACUUM
  • ISSN:   0042-207X
  • 通讯作者地址:   Univ Messina
  • 被引频次:   6
  • DOI:   10.1016/j.vacuum.2020.109175
  • 出版年:   2020

▎ 摘  要

The suitability of graphene oxide (GO) foils as radiation sensitive materials for soft X-ray irradiation is investigated by means of X-ray photoelectron spectroscopy (XPS). In particular GO micrometric foils have been irradiated by soft X-rays at a 1486.6 eV energy at high flux (>10(12) photons/cm(2)s) in ultra-high vacuum. The XPS analysis of the carbon-carbon (CC) and the carbon-oxygen links (CO) characterizes the composition of the first layers of the GO foils. The CC/CO ratio of the high-resolution C1s XPS spectrum is used as dosimetric index. The incident X-ray photons, proportionally to their fluence, partially reduce GO foils decreasing the amount of oxygen groups chemically bonded to carbon network. This decrease causes an increase on the CC/CO ratio that is correlated to the irradiation time, i.e. to the dose absorbed by the GO foil, showing a linear increment with the dose. Our preliminary investigations indicate that GO can be employed to realize a thin foil dosimeter giving a linear response to the absorbed dose in the (275.76 kGy divided by 8.02 MGy) range. The absorbed dose can be also evaluated by measuring the C/O ratio from the C1s and O1s XPS spectra analysis or with different techniques, as discussed in the paper.