• 文献标题:   Sodium cholate as efficient green reducing agent for graphene oxide via flow reaction for flexible supercapacitor electrodes
  • 文献类型:   Article
  • 作  者:   LAU KS, GINTING RT, TAN ST, CHIN SX, ZAKARIA S, CHIA CH
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCEMATERIALS IN ELECTRONICS
  • ISSN:   0957-4522 EI 1573-482X
  • 通讯作者地址:   Univ Kebangsaan Malaysia
  • 被引频次:   3
  • DOI:   10.1007/s10854-019-02275-z
  • 出版年:   2019

▎ 摘  要

In this work, sodium cholate (NaC) was used as novel green reducing agent for graphene oxide (GO) reduction at 90 degrees C and short synthesis time using a continuous segmented flow reaction system. As a comparison, we had used the common reducing agent which is glucose to study its chemical and electrochemical properties. The morphologies of GO and reduced-graphene oxide (rGO) were characterized with X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscope (FESEM), Fourier transformed infrared (FTIR), Raman and Ultraviolet-Visible (UV-Vis) spectroscopy analysis demonstrated that reduction of GO occurred. For electrochemical measurements, the rGO was cast on carbon cloth to investigate the electrochemical performance with cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) measurements. NaC assisted rGO (rGO-NaC) was able to achieve a specific capacitance up to 94 F g(-1) at 0.1 A g(-1) and remarkable capacitance retention of 103% after 10,000 cycles. A flexible test shows that rGO-NaC bendable at 0 degrees-60 degrees. These results demonstrate that rGO-NaC is promising as flexible supercapacitors electrodes.