• 文献标题:   The electrochemical performance of Ni-added Li3V2(PO4)(3)/graphene composites as cathode material for Li-ion batteries
  • 文献类型:   Article
  • 作  者:   CHOI M, KIM HS, LEE YM, JIN BS
  • 作者关键词:   lithium vanadium phosphate, graphene nanopowder, nickel, electrical conductivity, liion battery
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:   Korea Electrotechnol Res Inst
  • 被引频次:   6
  • DOI:   10.1016/j.matlet.2015.01.087
  • 出版年:   2015

▎ 摘  要

Ni-added Li3V2(PO4)(3)/graphene (Li3V2-xNix(PO4)(3), x=0.1, 0.2, and 03, LVNP) was easily synthesized by a facile sol-gel method. The addition of a graphene and Ni in Li3V2(PO4)(3) (LVP) showed the high crystallinity and influenced the morphology of the LVP particles. The effect of the addition of graphene and Ni was investigated in physical and electrochemical properties. Compared with the pristine LVP, the LVNP composite delivered a higher discharge capacity of 180 mA h g(-1) at 0.1 C-rate and better rate capability in the potential range of 3.0-4.8 V. The electrochemical impedance spectra (EIS) measurement, the resistance of LVP electrode was reduced, which can ensure the high specific capacity and rate capability. (C) 2015 Elsevier B.V. All rights reserved.