• 文献标题:   Synthesis of ultra-thin graphene-like nanosheets from lignin based on evaporation induced self-assembly for supercapacitors
  • 文献类型:   Article
  • 作  者:   LIANG YN, ZHOU YQ, LIU XN, QI XH
  • 作者关键词:   lignin, eisa, graphene, supercapacitor, biomas
  • 出版物名称:   INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
  • ISSN:   0141-8130 EI 1879-0003
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1016/j.ijbiomac.2023.123247 EA JAN 2023
  • 出版年:   2023

▎ 摘  要

Graphene-like carbon materials are widely used in power devices due to their excellent structural characteristics. In this study, ultra-thin graphene-like nanosheets (LGLNs) with rich surface wrinkles were prepared by classical evaporation induced self-assembly (EISA) using lignin biomass as carbon precursor, followed by chemical activation with KHCO3. The obtained LGLN(900) material calcined at 900 degrees C had a thickness of ca. 3 nm, a large specific surface area of 2886 m(2) g(-1) with a high specific pore volume of 2.10 cm3 g(-1). In addition, a large number of wrinkles on the surface of LGLN(900) endows its effective compression resistance. When the LGLN(900) material was used as electrode material of supercapacitor, a high specific capacitance of 388 F g(-1) was obtained at 0.2 A g(-1) current density in 6 M KOH aqueous solution, and 269 F g(-1)1 specific capacitance could be at remained at 40 A g(-1). The supercapacitor assembled with LGLN(900) afforded a specific energy density of (11.0-13.7) Wh kg(-1) at a power density of (128.8-6465) W kg(-1). This work provides a facile and green strategy for the synthesis of highly wrinkled ultra-thin graphene-like nanosheets from sustainable biomass resources, which should have wide applications in adsorption, catalysis and energy storage.