• 文献标题:   Synthesis of green-photoluminescent single layer graphene quantum dots: Determination of HOMO and LUMO energy states
  • 文献类型:   Article
  • 作  者:   BAYAT A, SAIEVARIRANIZAD E
  • 作者关键词:   single layer graphene quantum dot, cyclic voltammetry, band gap, glucose
  • 出版物名称:   JOURNAL OF LUMINESCENCE
  • ISSN:   0022-2313 EI 1872-7883
  • 通讯作者地址:   Tarbiat Modares Univ
  • 被引频次:   13
  • DOI:   10.1016/j.jlumin.2017.06.055
  • 出版年:   2017

▎ 摘  要

Low-cost and high-yield green-photoluminescent single layer graphene quantum dots (SLGQDs) synthesized with only DI water and glucose as precursor using a hydrothermal method. Atomic force microscopy proved that the graphene quantum dots are single layers and transmission electron microscopy images showed that the average width of SLGQDs is about 8 nm and optical characterization revealed that SLGQDs are highly photo luminescent. Highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) of the SLGQDs against vacuum determined using a cyclic voltammetry technique, and energy band gap was obtained similar to 2.9 and 3.1 eV from cyclic voltammetry and optical measurements, respectively.