• 文献标题:   Cu2+1O/graphene nanosheets supported on three dimensional copper foam for sensitive and efficient non-enzymatic detection of glucose
  • 文献类型:   Article
  • 作  者:   YANG L, LIU DP, CUI GM, XIE YM
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Univ Shanghai Sci Technol
  • 被引频次:   4
  • DOI:   10.1039/c7ra02011b
  • 出版年:   2017

▎ 摘  要

In situ growth of Cu2+1O (Cu2O with metal excess defects) was achieved through a facile hydrothermal process by employing porous Cu foam (CF) as substrate and the precursor, meanwhile, graphene nanosheets (GN) were deposited onto the Cu2+1O/Cu foam substrate. The GN/Cu2+1O/CF hybrid electrode provides a large accessible surface area, and contact between GN/Cu2+1O and current collector (Cu foam) with good conductivity facilitated electron/ion transport. When being used as a potential biosensor for nonenzyme glucose detection, cyclic voltammetry (CV) and amperometric electrochemical method to evaluate the electrocatalytic performance of GN/Cu2+1O/CF, and the GN/Cu2+1O/CF hybrid electrode exhibits multistage linear detection ranges with high sensitivity (3.076 mA mM (1) cm (2)) and the detection limit is 5 mM. Furthermore, the GN/Cu2+1O/CF electrode also presented excellent repeatability, stability and reproducibility and selectivity. The design of GN/Cu2+1O/CF hybrid electrode provided a useful strategy for design electrochemistry non-enzymatic biosensors.