• 文献标题:   Bimodal fiber diameter distributed graphene oxide/nylon-6 composite nanofibrous mats via electrospinning
  • 文献类型:   Article
  • 作  者:   PANT HR, PARK CH, TIJING LD, AMARJARGAL A, LEE DH, KIM CS
  • 作者关键词:   electrospinning, spiderwave, graphene oxide, nylon6, nanocomposite
  • 出版物名称:   COLLOIDS SURFACES APHYSICOCHEMICAL ENGINEERING ASPECTS
  • ISSN:   0927-7757 EI 1873-4359
  • 通讯作者地址:   Chonbuk Natl Univ
  • 被引频次:   52
  • DOI:   10.1016/j.colsurfa.2012.05.018
  • 出版年:   2012

▎ 摘  要

In this work, nylon-6 spider-wave-like nano-nets are fabricated by regulating the amount of graphene oxide (GO) in polymer solution during electrospinning. The spider-wave-like nano-nets that comprise interlinked thin (approximate to 14 nm diameter) and thick fibers (approximate to 192 nm diameter) are widely distributed throughout the mat when suitable amount of GO is blended with nylon-6 solution. The heterogeneous composite mats were composed of bimodal nanofibers in which pore diameter was sufficiently decreased. The acceleration in ionization and degradation of nylon-6 (due to formic acid) solution caused by well-dispersed GO sheet as well as the formation of hydrogen bond between nylon-6 molecules and GO sheet during electrospinning are proposed as the possible mechanisms for the formation of these spider-wave-like nano-nets. (c) 2012 Elsevier B.V. All rights reserved.