• 文献标题:   Intrinsic Response of Graphene Vapor Sensors
  • 文献类型:   Article
  • 作  者:   DAN YP, LU Y, KYBERT NJ, LUO ZT, JOHNSON ATC
  • 作者关键词:  
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Univ Penn
  • 被引频次:   659
  • DOI:   10.1021/nl8033637
  • 出版年:   2009

▎ 摘  要

Graphene is a two-dimensional material with extremely favorable chemical sensor properties. Conventional nanolithography typically leaves a resist residue on the graphene surface, whose impact on the sensor characteristics has not yet been determined. Here we show that the contamination layer chemically dopes the graphene, enhances carrier scattering, and acts as an absorbent layer that concentrates analyte molecules at the graphene surface, thereby enhancing the sensor response. We demonstrate a cleaning process that veriliably removes the contamination on the device structure and allows the intrinsic chemical responses of the graphene monolayer to be measured. These intrinsic responses are surprisingly small, even upon exposure to strong analytes such as ammonia vapor.