• 文献标题:   Graphenothermal reduction synthesis of 'exfoliated graphene oxide/iron (II) oxide' composite for anode application in lithium ion batteries
  • 文献类型:   Article
  • 作  者:   PETNIKOTA S, MARKA SK, BANERJEE A, REDDY MV, SRIKANTH VVSS, CHOWDARI BVR
  • 作者关键词:   graphene oxide, graphenothermal reduction, exfoliated graphene oxide/iron ii oxide, lithiumion batterie, anode, electrochemical propertie
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Natl Univ Singapore
  • 被引频次:   53
  • DOI:   10.1016/j.jpowsour.2015.05.075
  • 出版年:   2015

▎ 摘  要

Graphenothermal Reduction process is used to obtain exfoliated graphene oxide (EG)/iron (II) oxide (FeO) composite prepared at 650 degrees C for 5 h in argon. Structural and compositional analyses of the sample confirm the formation of EG/FeO composite. This composite shows a reversible capacity of 857 mAh g(-1) at a current rate of 50 mA g(-1) in the voltage range 0.005-3.0 V versus Li. An excellent capacity retention up to 60 cycles and high coulombic efficiency of 98% are also observed. Characteristic Fe2+/0 redox peaks observed in Cyclic Voltammetry measurement are explained in correlation with lithium storage mechanism. Thermal, electrical and impedance spectroscopy studies of EG/FeO composite are discussed in detail. Comparative electrochemical cycling studies of EG/FeO composite with Fe2O3 and Fe3O4 materials prepared under controlled conditions are also discussed. (C) 2015 Elsevier B.V. All rights reserved.