• 文献标题:   Physicochemical Characteristics of Nitrogen Sorption on High-Porous Powders of Graphene-Like Boron Nitride
  • 文献类型:   Article
  • 作  者:   GARBUZ VV, LOBUNETS TF, PETROVA VA, TOMILA TV, SUVOROVA LS
  • 作者关键词:   graphenelike boron nitride tbng, surface structure, impurity, boron oxonitride, treatment
  • 出版物名称:   POWDER METALLURGY METAL CERAMICS
  • ISSN:   1068-1302 EI 1573-9066
  • 通讯作者地址:   Natl Acad Sci Ukraine
  • 被引频次:   1
  • DOI:   10.1007/s11106-016-9817-9
  • 出版年:   2016

▎ 摘  要

The porous structure of graphene-like boron nitride t-BNg powders is qualified. The material is homogenous and micro-mesoporous, with pores being distributed in the range 3.53-4.12 nm corresponding to 55% volume and 60% specific surface area of mesopores. The specific surface area of micropores calculated with the Dubinin-Kadlets method (t-method) is 28.3 m(2)/g and the specific surface area of mesopores calculated with the Barrett-Joyner-Halenda method is 141 m(2)/g. Powders of graphene-like t-BNg synthesized from carbamide contain impurities of polycondensed flat particles of boron oxonitride. Impurities as a refined sublimate (white powder) are separated out of the washed and dried t-BNg powder by subsequent vacuum heat treatment at 540 K and pressure to ae1.0 Pa. The sublimate is identified as a heterocyclic six-membered dimer with molecular formula H(OH)[(BON)(2)](OH)H.