• 文献标题:   Catalytic properties of graphene-metal nanoparticle hybrid prepared using an aromatic amino acid as the reducing agent
  • 文献类型:   Article
  • 作  者:   ADHIKARI B, BANERJEE A
  • 作者关键词:   chemical synthesi, nanostructure, atomic force microscopy afm, electron microscopy tem sem, composite material, metal
  • 出版物名称:   MATERIALS CHEMISTRY PHYSICS
  • ISSN:   0254-0584 EI 1879-3312
  • 通讯作者地址:   Indian Assoc Cultivat Sci
  • 被引频次:   13
  • DOI:   10.1016/j.matchemphys.2013.01.020
  • 出版年:   2013

▎ 摘  要

An easy and single step process of making reduced graphene oxide nanosheet from graphene oxide (GO) in water medium has been demonstrated by using a naturally occurring non-proteinaceous amino acid (2,4-dihydroxy phenyl alanine, Dopa) as a new reducing agent and stabilizing agent This amino acid has also been used to reduce the noble metal salt (AuCl3/AgNO3) to produce the corresponding noble metal nanoparticles (MNP) without using any external reducing and stabilizing agents. So, this amino acid has been used to reduce simultaneously GO to RGO and noble metal salts to produce corresponding MNP to form RGO-MNP nanohybrid system in a single step in water medium and also in absence of any external toxic reducing and stabilizing agents. Different techniques UV-Visible absorption spectroscopy, X-ray diffraction, transmission electron microscopy, atomic force microscopy and others have been used to characterize the reduction of GO to RGO, metal salts to produce corresponding MNPs and the formation of RGO-MNP nanohybrid systems. Moreover, this metal nanoparticle containing RGO-MNP nanohybrid system acts as a potential catalyst for the reduction of aromatic nitro to aromatic amino group. (C) 2013 Elsevier B.V. All rights reserved.