• 文献标题:   One-step fabrication of heterogeneous conducting polymers-coated graphene oxide/carbon nanotubes composite films for high-performance supercapacitors
  • 文献类型:   Article
  • 作  者:   ZHOU HH, HAN GY
  • 作者关键词:   supercapacitor, conducting polymer, graphene oxide, carbon nanotube, composite
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Shanxi Univ
  • 被引频次:   40
  • DOI:   10.1016/j.electacta.2016.02.015
  • 出版年:   2016

▎ 摘  要

Composite films of heterogeneous conducting polymers-coated graphene oxide/carbon nanotubes (CPsGO/CNTs; CPs, PPy and PEDOT) have been fabricated via one-step electrochemical co-deposition. Scanning electron microscope and transmission electron microscopy characterizations indicate that the as-prepared CPs-GO/CNTs composites show a GO supported CPs-coated CNTs ternary hybrid microstructure. The electrochemical measurements including cyclic voltammetry, galvanostatic charge/discharge measurements, and electrochemical impedance spectroscopy tests manifest that the capacitive performances of CPs-GO electrodes are obviously promoted as the introduction of CNTs, and the PEDOT-GO/CNTs electrodes exhibit the more significantly improved electrochemical performances as the more CNTs introduced. Furthermore, the as-prepared PPy-GO/CNTs and PEDOT-GO/CNTs ternary composites achieve a high areal specific capacitance (142.2 mF cm(-2) and 99.0 mF cm(-2) at 1.0 mA cm(-2), respectively), together with superior rate capability, and excellent cycle stability (maintain 97.3% and 99.2% of initial capacitance for 5000 cycles, respectively), which are essential for their applications in high-performance supercapacitor electrodes. (C) 2016 Elsevier Ltd. All rights reserved.