• 文献标题:   A facile mold-free micromechanical method for patterning multilayer graphene by utilizing the difference in interfacial adhesion forces
  • 文献类型:   Article
  • 作  者:   RAGUL S, KRISHNAN D, DUTTA S, RAY D
  • 作者关键词:   graphene, patterning, multilayer, dft, adhesion
  • 出版物名称:   DIAMOND RELATED MATERIALS
  • ISSN:   0925-9635 EI 1879-0062
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1016/j.diamond.2021.108686 EA DEC 2021
  • 出版年:   2021

▎ 摘  要

We report a method to pattern graphene on silicon dioxide by a physical process utilizing its inter-facial properties with metal, silicon dioxide and polymer photoresist. The process utilizes the difference in adhesion energies of various interfaces between these materials with graphene. The mechanical forces involved in this process are strong enough to pattern multiple layers of graphene at once. As the sacrificial patterning layer is in flush contact with graphene, the process does not suffer from residual layers at the undesired sites, as in polymer based stamp transfer techniques. We have calculated the adhesion energies of these interfaces using density functional theory (DFT), theoretical estimation and experimental methods using Atomic Force Microscopy (AFM). These observations are in good agreement with each other and defend the feasibility of the proposed graphene patterning method.