• 文献标题:   Nitrene addition to exfoliated graphene: a one-step route to highly functionalized graphene
  • 文献类型:   Article
  • 作  者:   STROM TA, DILLON EP, HAMILTON CE, BARRON AR
  • 作者关键词:  
  • 出版物名称:   CHEMICAL COMMUNICATIONS
  • ISSN:   1359-7345 EI 1364-548X
  • 通讯作者地址:   Rice Univ
  • 被引频次:   93
  • DOI:   10.1039/c001488e
  • 出版年:   2010

▎ 摘  要

We demonstrate a high yield method of functionalizing graphene nanosheets through nitrene addition of azido-phenylalanine [Phe(N-3)] to exfoliated micro-crystalline graphite (mu G). This method provides a direct route to highly functionalized graphene sheets. TEM analysis of the product shows few layer (n < 5) graphene sheets. The product was determined to have 1 phenylalanine substituent per 13 carbons.