• 文献标题:   Electrochemical detection of dopamine using phthalocyanine-nitrogen-doped graphene quantum dot conjugates
  • 文献类型:   Article
  • 作  者:   NDEBELE N, SEN P, NYOKONG T
  • 作者关键词:   dopamine, nitrogendoped quantum dot, electrocatalyst, cobalt phthalocyanine
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:  
  • 被引频次:   6
  • DOI:   10.1016/j.jelechem.2021.115111 EA MAR 2021
  • 出版年:   2021

▎ 摘  要

Two cobalt phthalocyanine molecules were synthesized, a symmetrically substituted CoPc (1) and an unsymmetrically substituted CoPc (2). These CoPcs were z-z stacked onto nitrogen-doped graphene quantum dots (NGQDs). The CoPcs, NGQDs and their respective conjugates were used as electro-catalytic probes in the electrochemical oxidation of dopamine. The molecules were adsorbed onto a glassy carbon electrode (GCE) using the drop dry method, the GCE was used to support those catalysts. The electrooxidation of dopamine was studied using cyclic voltammetry and chronoamperometry. An improvement in the sensitivity and limit of detection was observed upon conjugation.