• 文献标题:   A highly efficient flocculant for graphene oxide recycling and its applications
  • 文献类型:   Article
  • 作  者:   LUAN RY, PAN H, MA YN, MAO L, LI Y, WANG DW, ZHANG D, ZHU SM
  • 作者关键词:   graphene oxide, recycling, zinc oxide, flocculant, supercapacitor
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Shanghai Jiao Tong Univ
  • 被引频次:   0
  • DOI:   10.1088/1361-6528/aa9a20
  • 出版年:   2018

▎ 摘  要

In this study, we found a novel and efficient way of recycling graphene oxide (GO) by adding ZnO colloid into the GO solution. GO flocculates immediately when mixed with ZnO colloids. Interestingly, the flocculation would disappear and disperse homogeneously in solution if a certain amount of HCl is added. The study offers a solution to recover and reuse GO throughout its production procedures. More importantly, in the obtained reduced GO/ZnO (rGO/ZnO) flocculant, ZnO nanorods are observed self-assembled into an ordered structure in between the rGO sheets. This prevents the rGO sheets from re-stacking and facilitates the movement of the electrolyte into ZnO if the prepared rGO/ZnO is used as an electrode for supercapacitor. Electrochemical measurements have proved that the rGO/ZnO composite with a weight ratio of 1: 1 exhibits a gravimetric specific capacitance of 175 F g(-1) and the rGO/ZnO electrode maintains 89.6% of the initial capacitance after 5000 cycles of uses.