• 文献标题:   Modified Graphene Sheet Stacks for Hydrogen Binding
  • 文献类型:   Article
  • 作  者:   LESNICENOKS P, ZEMITIS J, GRINBERGA L, CHIKVAIDZE G, KLEPERIS J, URBONAVICIUS M, TUCKUTE S, MILCIUS D
  • 作者关键词:   hydrogen storage, graphene, exfoliation, multisheet stack
  • 出版物名称:   MATERIALS SCIENCEMEDZIAGOTYRA
  • ISSN:   1392-1320 EI 2029-7289
  • 通讯作者地址:   Univ Latvia
  • 被引频次:   0
  • DOI:   10.5755/j.01.ms.23.1.13729
  • 出版年:   2017

▎ 摘  要

Graphene sheet stacks were obtained using electrochemical exfoliation method. The morphology, distribution of elements and structure of the obtained samples were investigated using scanning electron microscopy, energy dispersive spectroscopy, Raman spectroscopy and Brunauer-Emmett-Teller methods. The graphene sheet stacks mostly have been formed with open stack structures having surface area of 124 m(2)/g. Mg intercalation in graphene sheet structures was obtained adding MgCl2 during exfoliation process. Hydrogen desorption were measured in the temperature range 100 -473 K at the pressure 2 bar reaching maximal desorbed hydrogen amount of 0.12 - 0.43 wt.%.