• 文献标题:   Synthesis, Characterization, Electronic and Gas-Sensing Properties towards H2 and CO of Transparent, Large-Area, Low-Layer Graphene
  • 文献类型:   Article
  • 作  者:   KAYHAN E, PRASAD RM, GURLO A, YILMAZOGLU O, ENGSTLER J, IONESCU E, YOON S, WEIDENKAFF A, SCHNEIDER JJ
  • 作者关键词:   chemical vapor deposition, electrical propertie, graphene, raman spectroscopy, sensor
  • 出版物名称:   CHEMISTRYA EUROPEAN JOURNAL
  • ISSN:   0947-6539 EI 1521-3765
  • 通讯作者地址:   Tech Univ Darmstadt
  • 被引频次:   12
  • DOI:   10.1002/chem.201201880
  • 出版年:   2012

▎ 摘  要

Low-layered, transparent graphene is accessible by a chemical vapor deposition (CVD) technique on a Ni-catalyst layer, which is deposited on a < 100 > silicon substrate. The number of graphene layers on the substrate is controlled by the grain boundaries in the Ni-catalyst layer and can be studied by micro Raman analysis. Electrical studies showed a sheet resistance (Rsheet) of approximately 1435 Omega per square, a contact resistance (Rc) of about 127 Omega, and a specific contact resistance (R-sc) of approximately 2.8x10(-4) Omega cm(2) for the CVD graphene samples. Transistor output characteristics for the graphene sample demonstrated linear current/voltage behavior. A current versus voltage (IdsVds) plot clearly indicates a p-conducting characteristic of the synthesized graphene. Gas-sensor measurements revealed a high sensor activity of the low-layer graphene material towards H-2 and CO. At 300 degrees C, a sensor response of approximately 29 towards low H-2 concentrations (1 vol%) was observed, which is by a factor of four higher than recently reported.