• 文献标题:   Competing Ultrafast Energy Relaxation Pathways in Photoexcited Graphene
  • 文献类型:   Article
  • 作  者:   JENSEN SA, MICS Z, IVANOV I, VAROL HS, TURCHINOVICH D, KOPPENS FHL, BONN M, TIELROOIJ KJ
  • 作者关键词:   graphene, ultrafast, hot carrier, terahertz, pumpprobe
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   ICFO Inst Cencies Foton
  • 被引频次:   45
  • DOI:   10.1021/nl502740g
  • 出版年:   2014

▎ 摘  要

For most optoelectronic applications of graphene, a thorough understanding of the processes that govern energy relaxation of photoexcited carriers is essential. The ultrafast energy relaxation in graphene occurs through two competing pathways: carriercarrier scattering, creating an elevated carrier temperature, and optical phonon emission. At present, it is not clear what determines the dominating relaxation pathway. Here we reach a unifying picture of the ultrafast energy relaxation by investigating the terahertz photoconductivity, while varying the Fermi energy, photon energy and fluence over a wide range. We find that sufficiently low fluence (less than or similar to 4 mu J/cm(2)) in conjunction with sufficiently high Fermi energy (greater than or similar to 0.1 eV) gives rise to energy relaxation that is dominated by carriercarrier scattering, which leads to efficient carrier heating. Upon increasing the fluence or decreasing the Fermi energy, the carrier heating efficiency decreases, presumably due to energy relaxation that becomes increasingly dominated by phonon emission. Carrier heating through carriercarrier scattering accounts for the negative photoconductivity for doped graphene observed at terahertz frequencies. We present a simple model that reproduces the data for a wide range of Fermi levels and excitation energies and allows us to qualitatively assess how the branching ratio between the two distinct relaxation pathways depends on excitation fluence and Fermi energy.