• 文献标题:   Supercapacitors Based on Flexible Graphene/Polyaniline Nanofiber Composite Films
  • 文献类型:   Article
  • 作  者:   WU Q, XU YX, YAO ZY, LIU AR, SHI GQ
  • 作者关键词:   graphene, polyaniline nanofiber, supercapacitor, composite, flexible
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   1603
  • DOI:   10.1021/nn1000035
  • 出版年:   2010

▎ 摘  要

Composite films of chemically converted graphene (CCG) and polyaniline nanofibers (PANI-NFs) were prepared by vacuum filtration the mixed dispersions of both components. The composite film has a layered structure, and PANI-NFs are sandwiched between CCG layers. Furthermore, it is mechanically stable and has a high flexibility; thus, it can be bent into large angles or be shaped into various desired structures. The conductivity of the composite film containing 44% CCG (5.5 x 10(2) S m(-1)) is about 10 times that of a PANI-NF film. Supercapacitor devices based on this conductive flexible composite film showed large electrochemical capacitance (210 F g(-1)) at a discharge rate of 0.3 A g(-1). They also exhibited greatly improved electrochemical stability and rate performances.