• 文献标题:   Controllable growth of graphene dendrite and application to electrochemical capacitors
  • 文献类型:   Article
  • 作  者:   LIU YY, ZHANG JJ, SHANG Y, LIU Y, ZHANG D
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCEMATERIALS IN ELECTRONICS
  • ISSN:   0957-4522 EI 1573-482X
  • 通讯作者地址:   Tongji Univ
  • 被引频次:   0
  • DOI:   10.1007/s10854-015-2989-0
  • 出版年:   2015

▎ 摘  要

Synthesis of graphene dendrites with controlled morphologies (flower-like and tree-like) were achieved by changing applied potential in electrochemical reaction. The growth of graphene dendrites proceeded with two different oriented attachment modes. When applied potential a parts per thousand currency sign60 V, graphene nanosheets preferentially extended into branches, resulting in the formation of flower-like dendrites. While applied potential a parts per thousand yen60 V, more graphene nanosheets were produced on electrode and grew along the stem directions, leading to the formation of tree-like dendrites. Moreover, the effects of different morphology of graphene dendrite on its electrochemical performances were investigated. The results showed that tree-like dendrite electrode had a larger specific capacitance (138 F/g at 100 mv/s) than that of flower-like dendrite electrode. Generally, graphene dendrites with controlled morphologies might have promising applications as electrode materials for supercapacitors.