• 文献标题:   Nitrogen-doped graphene supported NiFe2O4 nanoparticles as high-performance anode material for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   PAN SG, ZHAO XM
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCEMATERIALS IN ELECTRONICS
  • ISSN:   0957-4522 EI 1573-482X
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1007/s10854-021-07066-z EA SEP 2021
  • 出版年:   2021

▎ 摘  要

Nitrogen-doped graphene supported NiFe2O4 nanoparticles (NiFe2O4-NG) composite was successfully synthesized by a simple hydrothermal method. In the NiFe2O4-NG nanocomposite, the surface of nitrogen-doped graphene sheets was loaded by a large number of uniform NiFe2O4 nanoparticles with the mean size of 8 nm. Meanwhile, the nitrogen-doped graphene sheets were exfoliated. As anode materials for lithium ion batteries, the initial discharge and charging capacities of NiFe2O4-NG electrode are 1888 and 1242 mAh g(-1), respectively, and the coulomb efficiency is 65.8%. Furthermore, the capacity of NiFe2O4-NG is 1100 mAh g(-1) after 50 cycles. Compared with pure NiFe2O4, the superior electrochemical performance of the NiFe2O4-NG nanocomposite is mainly attributed to the unique architecture of smaller NiFe2O4 nanoparticles loaded on the high conductivity of nitrogen-doped graphene sheets, as well as the synergy effect between the nitrogen-doped graphene and nanoparticles. The high specific surface area of NiFe2O4-NG can increase the interface area between electrode and electrolyte, ensuring the full contact between electrode surface and electrolyte. The strong interaction between nitrogen-doped graphene and nanoparticle is beneficial to effectively suppress the volume expansion and the rapid ion/electron transport during the charge-discharge process. Profiting from structure and composition characteristics, the above-mentioned NiFe2O4-NG electrode delivers an excellent capacity, cycle performance and rate capability.