• 文献标题:   Surfactant-modified chemically reduced graphene oxide for electrochemical supercapacitors
  • 文献类型:   Article
  • 作  者:   KE QQ, LIU YQ, LIU HJ, ZHANG Y, HU YT, WANG J
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Natl Univ Singapore
  • 被引频次:   39
  • DOI:   10.1039/c4ra03826f
  • 出版年:   2014

▎ 摘  要

An easy method to synthesize surfactant-modified graphene for a supercapacitor is demonstrated through the intercalation of graphene oxide (GO) with a triblock copolymer Pluronic F127 (F127). A rationalized, reduced GO-F127 is obtained by hydrothermal and thermal annealing-driven structural reconstruction. The F127 successfully intercalates into the GO layers and facilitates the stabilization of the single-layer or few-layer structure of graphene sheets during the reduction process. An increased surface area of 696 m(2) g(-1) is achieved in the surfactant-modified graphene, which is about three times higher than that of pristine graphene (200 m(2) g(-1)). The electrocapacitive behaviors of the resultant composites are systematically investigated by cyclic voltammetry and galvanostatic charge-discharge techniques. The rGO-F127 sample thermal-treated at 400 degrees C delivers a maximum specific capacitance of 210 F g(-1) at a scanning rate of 1 mV s(-1) in 6 M KOH electrolyte and has an excellent cycling stability, retaining over 95.6% of the initial capacity after 1000 cycles.