• 文献标题:   Graphene-based nitrogen-doped carbon sandwich nanosheets: a new capacitive process controlled anode material for high-performance sodium-ion batteries
  • 文献类型:   Article
  • 作  者:   LI DD, ZHANG L, CHEN HB, WANG J, DING LX, WANG SQ, ASHMAN PJ, WANG HH
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   S China Univ Technol
  • 被引频次:   92
  • DOI:   10.1039/c6ta02139e
  • 出版年:   2016

▎ 摘  要

Anode materials with capacitive charge storage (CCS) are highly desirable for the development of high-performance sodium-ion batteries (SIBs), because the capacitive process usually shows kinetically high ion diffusion and superior structural stability. Here, we report a new CCS anode material of graphene-based nitrogen-doped carbon sandwich nanosheets (G-NCs). The as-prepared G-NCs show a high capacitive contribution during the discharge/charge processes. As expected, the G-NCs exhibit excellent rate performance with a reversible capacity of 110 mA h g(-1), even at a current as high as 10 000 mA g(-1) and outstanding cycle stability (a retention of 154 mA h g(-1) after 10 000 cycles at 5000 mA g(-1)). This represents the best cycle stability among all reported carbon anode materials for SIBs, thereby showing great potential as a commercial anode material for SIBs.