• 文献标题:   Visible light photocatalysis of Methylene blue by graphene-based ZnO and Ag/AgCl nanocomposites
  • 文献类型:   Article
  • 作  者:   VANITHA M, KEERTHI, VADIVEL S, BALASUBRAMANIAN N
  • 作者关键词:   photocatalyst, graphene, visible light, surface plasmon resonance, methylene blue
  • 出版物名称:   DESALINATION WATER TREATMENT
  • ISSN:   1944-3994 EI 1944-3986
  • 通讯作者地址:   Anna Univ
  • 被引频次:   6
  • DOI:   10.1080/19443994.2014.903207
  • 出版年:   2015

▎ 摘  要

The present investigation deals with the photocatalytic activity of two different graphene oxide-(GO) based nanocomposites i.e. Ag/AgCl/GO and ZnO/GO for the degradation of Methylene blue (MB). The composites were prepared by low-temperature hydrothermal method and were characterized using scanning electron microscope (SEM), X-ray diffraction (XRD), and Raman spectroscopy. SEM analysis showed that GO was stacked between the hexagonal ZnO nanostructures and in the case of Ag/AgCl, it was grafted onto the distorted spheres of Ag/AgCl. This distorted structure may be due to the overloading of the silver precursor close to the saturation during the synthesis. XRD pattern confirms the formation of both the nanocomposites. Both the nanocomposites showed good performance in degrading the dye under sunlight. ZnO/GO being a semiconductor photocatalyst showed 95% removal of dye in 100 min, whereas plasmonic catalyst Ag/AgCl/GO was found to degrade 92% of MB within 50 min of reaction time due to its unique surface plasmon resonance property. Raman spectroscopy confirms the enhanced photocatalytic activity of both the nanocomposites, which is due to the electron-accepting property of the GO and hinders the recombination of electron-hole pair.