• 文献标题:   Synthesis of graphene oxide decorated with strontium oxide (SrO/GO) as an efficient nanocomposite for removal of hazardous ammonia from wastewater
  • 文献类型:   Article
  • 作  者:   MOUSAVI SV, BIDHENDI GN, MEHRDADI N
  • 作者关键词:   strontium nanoparticle, graphene oxide, ammonia, adsorption, kinetic adsorption isotherm
  • 出版物名称:   SEPARATION SCIENCE TECHNOLOGY
  • ISSN:   0149-6395 EI 1520-5754
  • 通讯作者地址:   Univ Tehran
  • 被引频次:   1
  • DOI:   10.1080/01496395.2019.1601218 EA MAY 2019
  • 出版年:   2020

▎ 摘  要

In this research, graphene oxide decorated with strontium oxide (SrO/GO) is introduced as a new adsorbent material for the efficient removal of ammonia from industrial wastewater. The new adsorbent was thoroughly studied in terms of morphology, crystallography and chemical composition using characterization techniques such as Fourier transform infrared (FTIR), X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and zeta potential analysis. Several parameters such as pH, adsorbent dosage, contact time, and ammonia initial concentration were investigated and optimized. Ammonia adsorption onto SrO/GO was validated with kinetics and adsorption isotherms by adopting different models. The results revealed that ammonia adsorption kinetic was of pseudo-second order (R-2 = 0.999) implying that chemisorption behavior and the equilibrium isotherm follows Langmuir model. This behavior shows a high maximum monolayer sorption capacity of 90.1 mg g(-1) at pH equal to 7 and contact time of 120 min pointing out the synergism advantageous effect. The abundant oxygen functional groups on the graphene oxide surface and the integrated Sr-O nanoparticles could efficiently interact with ammonia species creating a surface for more favorable and efficient removal of ammonia.