• 文献标题:   Reinforcing polyamide 1212 with graphene oxide via a two-step melt compounding process
  • 文献类型:   Article
  • 作  者:   CAI ZQ, MENG XY, HAN YS, YE HM, CUI LS, ZHOU Q
  • 作者关键词:   polymermatrix composite, mechanical propertie, directional orientation graphene oxide
  • 出版物名称:   COMPOSITES PART AAPPLIED SCIENCE MANUFACTURING
  • ISSN:   1359-835X EI 1878-5840
  • 通讯作者地址:   China Univ Petr
  • 被引频次:   16
  • DOI:   10.1016/j.compositesa.2014.11.011
  • 出版年:   2015

▎ 摘  要

In this study, graphene oxide (GO) was synthesized from graphite powders via Hummers' method. Polyamide 1212 (PA1212)/GO composites were prepared via a two-step melt compounding process. First, GO concentrates were prepared via solution coagulation. In this method, a GO solution was mixed with an ethanol-soluble polyamide solution. The resulting product was melt-compounded with a PA1212 matrix. This method enabled GO nanosheets to be well-dispersed in a PA1212 matrix. GO, which functioned as a nucleation template, exhibited heterogeneous nucleation effect in the PA1212 matrix because of its large specific surface area. The mechanical properties of the oriented PA1212/GO composites improved efficiently compared with those of pure PA1212. Crystal orientation degree and crystallinity in the composites increased slightly when GO was added after drawing. The composites' reinforcing effect was mainly attributed to GO nanosheet alignment. These nanonsheets functioned as the nuclei to reinforce the entire oriented crystals. (C) 2014 Elsevier Ltd. All rights reserved.