• 文献标题:   Impedance Spectroscopy-Based Reduced Graphene Oxide-Incorporated ZnO Composite Sensor for H2S Investigations
  • 文献类型:   Article
  • 作  者:   BALASUBRAMANI V, SURESHKUMAR S, RAO TS, SRIDHAR TM
  • 作者关键词:  
  • 出版物名称:   ACS OMEGA
  • ISSN:   2470-1343
  • 通讯作者地址:   Univ Madras
  • 被引频次:   4
  • DOI:   10.1021/acsomega.9b00754
  • 出版年:   2019

▎ 摘  要

Electrochemical impedance spectroscopy (EIS) has been applied to measure the H2S gas response of the sensor fabricated on reduced graphene oxide (rGO)-incorporated nano-zinc oxide (n-ZnO) composites. These nanocomposites were prepared by a facile one-step solution route at room temperature. The structural, surface morphological, and elemental analyses of the composite material have been investigated. EIS was carried out to study the H2S gas-sensing properties of fabricated sensors. The developed sensor showed an optimal H2S gas response to various concentrations ranging from 2 to 100 ppm at 90 degrees C. The H2S gas-sensing performances of pure n-ZnO and various concentrations of rGO-incorporated n-ZnO were evaluated. The H2S gas-sensing results showed that n-ZnO/rGO composites exhibited high response when compared to pure n-ZnO. The enhanced H2S response was speculated to be ascribed due to two factors. First, rGO creates reactive sites for H2S molecule adsorption. Second, rGO has great electrical conductivity compared to n-ZnO that enables the active transport of electrons from H2S gas on interaction with the sensing layer, resulting in enhanced gas response at 90 degrees C temperatures.