• 文献标题:   Carbon gel assisted low temperature liquid-phase synthesis of CLiFePO4/graphene layers with high rate and cycle performances
  • 文献类型:   Article
  • 作  者:   TANG HW, SI YL, CHANG K, FU XN, LI B, SHANGGUAN EB, CHANG ZR, YUAN XZ, WANG HJ
  • 作者关键词:   low temperature synthesi, liquidphase method, lithium ion battery, lithium iron phosphate, graphene oxide
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Henan Normal Univ
  • 被引频次:   15
  • DOI:   10.1016/j.jpowsour.2015.06.145
  • 出版年:   2015

▎ 摘  要

Nano-scale LiFePO4/graphene oxide (GO) as cathode materials for lithium ion batteries has been successfully synthesized via a one-step carbon gel assisted liquid-phase approach at a low-temperature (108 degrees C) and normal pressure. C-LiFePO4/graphene layers (G) composites, composed of LiFePO4, amorphous carbon and graphene layers, are then produced after rapid high temperature carbon treatment. Interface tunnel effect, produced by the intimate contact of LiFePO4 particles with amorphous carbon and graphene layers, greatly improves the properties of the composites. Electrochemical tests indicate that the optimal amount of GO addition is 1 wt.% in terms of achieving a high electrochemical performance of the C-LiFePO4/G composites. Discharge capacity of the C-LiFePO4/G composites is 160.0 mAh g-1 at 0.2 degrees C. When the current rate is further increased to 60 degrees C, the discharge capacity of C-LiFePO4/G can reach 68 mAh g. At a high current rate of 20 degrees C, the capacity attenuation rate of the C-LiFePO4/G electrode is only 9.6% after 200 cycles, showing excellent high-rate discharge capability and cycle performance. This is achieved under a facile synthesis condition of a simple procedure, low temperature, and normal pressure. (C) 2015 Elsevier B.V. All rights reserved.