• 文献标题:   A Self-assembled L-Cysteine and Electrodeposited Gold Nanoparticles-reduced Graphene Oxide Modified Electrode for Adsorptive Stripping Determination of Copper
  • 文献类型:   Article
  • 作  者:   XU YW, ZHANG W, HUANG XW, SHI JY, ZOU XB, LI YX, CUI XP, TAHIR HE, LI ZH
  • 作者关键词:   electrochemical sensor, lcysteine, gold nanoparticle, reduced graphene oxide, copper
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   Jiangsu Univ
  • 被引频次:   3
  • DOI:   10.1002/elan.201700637
  • 出版年:   2018

▎ 摘  要

Glassy carbon electrode (GCE) modified with L-cysteine and gold nanoparticles-reduced graphene oxide (AuNPs-RGO) composite was fabricated as a novel electrochemical sensor for the determination of Cu2+. The AuNPs-RGO composite was formed on GCE surface by electrodeposition. The L-cysteine was decorated on AuNPs by self-assembly. Physicochemical and electrochemical properties of L-cysteine/AuNPs-RGO/GCE were characterized by scanning electron microscopy, atomic force microscopy, energy dispersive spectroscopy, Raman spectroscopy, X-ray diffraction, cyclic voltammetry and adsorptive stripping voltammetry. The results validated that the prepared electrode had many attractive features, such as large electroactive area, good electrical conductivity and high sensitivity. Experimental conditions, including electrodeposition cycle, self-assembly time, electrolyte pH and preconcentration time were studied and optimized. Stripping signals obtained from L-cysteine/AuNPs-RGO/GCE exhibited good linear relationship with Cu2+ concentrations in the range from 2 to 60gL(-1), with a detection limit of 0.037gL(-1). Finally, the prepared electrode was applied for the determination of Cu2+ in soil samples, and the results were in agreement with those obtained by inductively coupled plasma mass spectrometry.