• 文献标题:   Facile synthesis of PdSnCo/nitrogen-doped reduced graphene as a highly active catalyst for lithium-air batteries
  • 文献类型:   Article
  • 作  者:   REN XZ, LIAO BY, LI YL, ZHANG PX, DENG LB, GAO Y
  • 作者关键词:   electrocatalyst, oxygen reduction reaction, lithiumair battery, nitrogendoped graphene, solvothermal
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Shenzhen Univ
  • 被引频次:   19
  • DOI:   10.1016/j.electacta.2017.01.032
  • 出版年:   2017

▎ 摘  要

Well-dispersed trimetallic-alloyed PdSnCo nanocrystals with an average size of 7 nm are supported on nitrogen-doped reduced graphene (NG) nanosheets by a solvothermal method. The PdSnCo/NG nanocatalyst is characterized by scanning electron microscopy, energy dispersive spectroscopy, transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. As a result, the PdSnCo/NG exhibits high catalytic activity toward oxygen reduction reaction and high electrochemical stability in alkaline medium, compared to commercial 10% Pd black, binary PdSn/NG, and PdCo/NG. Moreover, PdSnCo/NG nanocatalyst shows high discharge capacity of 6750 mAh g(-1), low charge voltage and predominant cycleability for lithium-air batteries. (C) 2017 Elsevier Ltd. All rights reserved.