• 文献标题:   Benzoyl hydrazine-anchored graphene oxide as supercapacitor electrodes
  • 文献类型:   Article
  • 作  者:   JOSE J, JOSE S, ABINAYA S, SHAJI S, SREEJA PB
  • 作者关键词:   energy storage, heteroatom, functional group, aqueous electrolyte
  • 出版物名称:   MATERIALS CHEMISTRY PHYSICS
  • ISSN:   0254-0584 EI 1879-3312
  • 通讯作者地址:   CHRIST Deemed Be Univ
  • 被引频次:   0
  • DOI:   10.1016/j.matchemphys.2020.123666
  • 出版年:   2020

▎ 摘  要

In this study, benzoyl-hydrazine anchored graphene oxide (BHGO) is synthesised using graphene oxide (GO) and benzoyl hydrazine (BH) via a simple, cost effective ultrasonic assisted chemical route. BH acted as a nitrogen source, reducing agent, and morphology modifier resulting in good electrochemical performance of BHGO. The supercapacitor behaviour of BHGO is investigated in different aqueous electrolytes and it exhibits a specific capacitance of 170 F g(-1) at a current density of 1 A g(-1) in 1 M H2SO4 and capacitive retention of 85% over 5000 cycles at 5 A g(-1). This high performance is attributed to the enrichment of electroactive sites of GO through nitrogen moieties enhancing faradaic redox reactions and thereby the polarization at the electrode surface.