• 文献标题:   Reduced graphene oxide networks as an effective buffer matrix to improve the electrode performance of porous NiCo2O4 nanoplates for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   CHEN YJ, ZHUO M, DENG JW, XU Z, LI QH, WANG TH
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Hunan Univ
  • 被引频次:   107
  • DOI:   10.1039/c3ta14624c
  • 出版年:   2014

▎ 摘  要

Transition metal oxides are promising high-capacity anode materials for next-generation lithium-ion batteries. However, their cycle life remains a limiting factor with respect to their commercial applications. The development of transition-metal oxide anode materials with long lifespans through a facile route has become an important issue. A straightforward strategy is designed for the fabrication of a NiCo2O4 nanoplates-reduced graphene oxide sheets (NiCo2O4-RGO) composite. It displays a high reversible capacity of 816 mA h g(-1) over 70 cycles with 80.1% capacity retention of the 2nd cycle and excellent rate capability. Its rate capability and cycling stability are enhanced in comparison with those of pure NiCo2O4 nanoplates. The as-obtained nanocomposite avoids the problems of dispersion and aggregation induced by cracking or pulverization of the transition-metal oxide upon cycling. The graphene or reduced graphene oxide not only works as a substrate to provide room for loading scattered grains, but also serves as a conductive network to facilitate the collection and transportation of electrons during the cycling, indirectly increasing the conductivity of NiCo2O4.